The following is a list prepared by the chapter of all the known/identified past presidents of the K. M. Van Zandt Chapter.
| President | Term | |
|---|---|---|
| Elmer Renfro | 1932 | Deceased |
| Frederick Carter Cutter | 1939 | Deceased |
| Cornelius Burnham Savage | 1946 | Deceased |
| Robert Garnett Waggener | 1947-1948 | Deceased |
| John Webster Naylor, Sr. | 1949 | Deceased |
| Chalmers Wyeth Hutchison | 1950 | Deceased |
| Harold Grey Neely | 1951 | Deceased |
| Robb Roy Stegall | 1952 | Deceased |
| William Morton Downes Cecil | 1953 | Deceased |
| Dr. William Curtis Nunn | 1954 | Deceased |
| William Charles Preston, Jr. | 1955 | Deceased |
| Marvin Curtis Nichols | 1956 | Deceased |
| Joseph Platt Gudger | 1957 | Deceased |
| Col. Uel Stephens, Jr. | 1957 | Deceased |
| Lorin Albert Boswell | 1958 | Deceased |
| Elton Marvin Hyder, Sr. | 1959 | Deceased |
| Wray Douglas Brown | 1960-1961 | Deceased |
| Robert Wright Armstrong, Jr. | 1962 | Deceased |
| Dr. James Franklin Campbell | 1963 | Deceased |
| Billy Couts Hutcheson | 1963 | Deceased |
| Hubert James Foster, Sr. | 1964 | Deceased |
| Dr. John David Pumphrey, M.D. | 1965-1966 | Deceased |
| Christopher Leslie Larkin | 1967 | Deceased |
| Col. Karl Edward Wallace, Sr. | 1968-1969 | Deceased |
| William Lewis Love | 1970 | Deceased |
| George Collins Thompson, Jr. | 1971 | Deceased |
| Brig. Gen. Lynn Marshall Yeatts | 1972 | Deceased |
| Lt. Col. Stanton Crocker Parker | 1972 | Deceased |
| Sam Woody Acola | 1973-1974 | Deceased |
| Col. James Longstreet Sibley Jennings | 1974-1975 | Deceased |
| George Collins Thompson, Jr. | 1976-1977 | Deceased |
| Kenneth Roston Cox | 1977-1978 | |
| William Harold Thompson | 1978-1980 | Deceased |
| Warren Clarke Russell | 1981 | |
| James Reagan Herman, Jr. | 1982-1983 | Deceased |
| Rev. Curren Rogers McLane | 1984 | Deceased |
| Hugh Dixon McKay, Jr. | 1985 | Deceased |
| George Wesley Demeritt | 1986 | Deceased |
| Harold Richard Bost | 1987-1988 | Deceased |
| Hugh Dixon McKay, Jr. | 1989 | Deceased |
| Robert Charles Holloway | 1990 | |
| James Manley Head, Jr. | 1991 | Deceased |
| Walter Scott Manning, Jr., D.V.M. | 1992-1993 | |
| Henry Fletcher Ball, Jr. | 1994-1995 | Deceased |
| Robert Mathews Daley | 1995 | |
| Donald George Pray | 1996 | Deceased |
| Edward Perryman Maddox, III, D.V.M. | 1997-1998 | Deceased |
| Robert Ralph Truitt, Sr. | 1999-2001 | Deceased |
| James Edward Alderman | 2001-2003 | |
| Donald Patrick Goodman, PHD | 2003-2005 | Deceased |
| James Emmett Haynes, Sr. | 2005-2007 | |
| Bobby Gene Shields | 2007-2008 | Deceased |
| Thomas Clyde McMurray | 2008-2009 | Deceased |
| Robert Ralph Truitt, Sr. | 2009-2010 | Deceased |
| Luther Vaughn Oliver | 2010-2011 | |
| Raymond Lee Leftwich | 2012-2013 | |
| Russell Warren Leavens | 2014-2015 | Deceased |
| Lawrence Michael Connelley | 2016-2017 | |
| Gerald Allen Gieger | 2018-2019 | |
| Ronald Joe Turner | 2020-2021 | |
| Robert Grady Gresham | 2022-2023 | |
| Ronald Joe Turner | 2024-2025 | |
| Steven James Hole | 2026- |
